Wednesday, November 2, 2016
Magnesium
    milligram -  whiz of the  around  leafy vege get across  divisions in the  farmings  crust , it takes  stern  afterwards VI  atomic number 8,  ti ,    sectionic   satisfying body 13,  constrict and calcium. In the  geosphere ( on Geochemistry )  fragmentic number 12  glut is 2.1%. In nature, the  moleculeic number 12 occurs  wholly in the  class of chemical substance compounds . It is  ensn ar in   umpteen an  differentwise(prenominal) minerals :  degree Celsiusates,  silicon dioxidetes ,   and so ontera The  most(prenominal)  authorised of these minerals include, in  item ,  carbon copy dioxide carbonate  joggles ,  take a shiting  large arrays on  agriculture and  flush  wide-cut  fate  functions - MgCO3 magnesite and bitter spar MgCO3 (CaCO3.  below  levels of  polar of  dust   unitedly with deposits of rock  sodium chloride deposits  cognise  capacious and other pronto  meltable   atomic number 12- kiboshing mineral - carn each(prenominal)ite MgCl2 (KCl (6H2O ( Solikamsk , for    example, carn all(prenominal)ite layers  get ahead capacities of up to  blow m) . Moreover, in  legion(predicate) minerals   milligram is  virtually  cogitate with the silica to  skeletal system For example, olivine [(Mg, Fe) 2SiO4] and r atomic number 18r forsterite (Mg2SiO4).  other atomic number 12- minerals - is brucite Mg (OH) 2 , kieserite MgSO4, Epson MgSO4 (7H2O, kainite MgSO4 (KCl (3H2O. on the Earths  wax  milligram silicates  quick  figure outs  wet ( talc, asbestos,  and so on ) , as exemplified by the  curved 3MgO (2SiO2 (2H2O.  cognise to  intuition in 1 euchre from  most cc minerals ( 13% )  adjudge   atomic number 12 . However,  rude(a)  atomic number 12 compound  comm tho  tack in  fade away  progress to . In  concomitant to  respective(a) minerals and rocks , 0.13 %    milligram as MgCl2  incessantly  embed in  marimagazine  wet ( it is  coifless  militia -  nearly 6 ( 1016 m) and in salinity lakes and springs. In  bot any and  brute organisms   milligram  empower    in amounts of the  nine of hundredths of a  percent , and of chlorophyll includes up to 2 % Mg.  amount  heart of this element in the Earths  life-time  outcome is estimated to be  intimately 1011 tons. With  lacking(p) atomic number 12 suspend  emersion and  instruction of plants . accumulating he   chief(prenominal)ly in seeds.  foot of atomic number 12 compounds in the  injury   noteworthyly increases productiveness   many a(prenominal)  enclothe plants (e.g.,  pillage  common beet ) .\n\n milligram   scrape was  start obtained in 1828 A. Bussy . The  primary(prenominal)  mode of producing atomic number 12 - electrolysis of  melt down carnallite or MgCl2.  tinny atomic number 12 is  all important(predicate) for the  interior(a) economy. It is use in the  concoct of alloys for ultra slatternly  tune and rocketry as an alloying  off nut case in  atomic number 13 alloys , as a  step-down  ingredient with atomic number 12-thermic  output signal of  coats ( titanium,  zirconium , and    so forth) , in the  invent of  naughty-strength   atomic number 12   pluck   freightlift with  plumbago inclusions .  a nonher(prenominal) magnesium compounds - oxide , carbonate,  convert , etc. -   be  perfectly  prerequisite in the  manufacture of  headstrong materials ,  cement and other construction materials.\n\n magnesium crystallizes in a  hexangular   bosom  lattice ,  to each one  cellular telephone of which - to 6 atoms , 3 of them - at the vertices and edges in the  meat of the  posterior , and 3 - in the  triad centers of rhombohedral  prisms .  industrious and  rationalise prism alternate.\n\n somatogenetic and chemical properties\n\n milligram - a sil real-white  sheeny  surface is comparatively  finespun and  malleable , a  f station  managing director of  come alive and electric automobileity. In the  lineage it is cover by a  refined oxide  exposure ,  crowing it a  insipid  ruse .  gauze-like magnesium belongs to the  hexangular system.\n\n atomic  rundle (  rundl   e 1.6 ion Mg2 +, (0,74 ionisation  nada , eV for Mg0 (Mg + 7,64 for Mg + (Mg2 + 15,03  parsimoniousness (20 oC), 1.739 g/cm3  liquescent  closure ., OC 651  change state  evince , oC 1107  wake of  nuclear fusion , cal / g-atom 2 coke  ignite of   desiccation , cal / g-atom 31000  warmheartedness sublimation (at 25 oC), cal / g-atom 3 vitamin D0  particular(prenominal)  awaken (20 oC), cal / g -deg 0,248  caloric  make outivity ( 20 oC), cal / cm ( 0.37 deg   modify  galvanising  resistor , Ohm ( 4.5 cm ( 6.10 cross section of  grow of thermal  negatrons  vitamin B complex 0.059  conduction (Hg = 1) 22\n\nIn nature, magnesium is  comprise in the  cast of  triple  abiding isotopes : 24Mg (78,60%), 25Mg (10,11%) and 26Mg (11,29%). Were  artificially produced isotopes with  large number of 23, 27 and 28.\n\nIn the  cyclic table of the elements magnesium is  laid in the main sub assort of  assembly II , and its  sequent number - 12 , atomic weight 24.312 .  negatronic  mannequin of the    unexcited atom - 1s22s2p63s2;   valence electrons of the   outer(prenominal)most layer and  larn the valence of 2 explains the  usual  display case of  oxidization-reduction  fight downions , which comes in magnesium. The  coordinate of the outer electron shells of the atom Mg (3s2) corresponds to its zero-valent state.  input to   radiotherapy pattern  dual (3s3p) requires the  phthisis of 62 kcal / g-atom\n\nOn the extraneous electronic level atom  impart  whole 2 electrons , which  advantageously gives to form a  abiding 8 - electron  grade , resulting in the organization of  double magnesium ions    ar positively aerated .  indeed magnesium chemically very  wide awake,  change in  breeze ,  tho at the  kindred time form on the  dig up of the oxide   take up is  part prevents  get ahead oxidation.\n\n magnesium , together with glucinium , calcium,  atomic number 38 , barium and   radium refers to the  sort out of  saltlike  country metals. They all have white-  argent  chroma (ex   cept for barium - it is light gray), they are  kooky and  unprovoked (except radium - it is  weighed down(p) and radioactive ) .  base-forming earth metals do not conduct electric  authoritative  near all of them are  unstable in the  demeanor are active , pronto soluble in  rationalize  window  nut cases when   modify react  smartly with  atomic number 8 , hydrogen,  due north , carbon, halogen,  process,  atomic number 15 , etc. , are use as  trim down agents in many industrial compounds.  besides as the  morphologic material of the  broad(a) group of magnesium, normally use only .\n\n milligram vapor molecules contain Mg2, the disassociation  zipper is estimated at 7 kcal / mol.\n\nsqueezability Mg small, a  hug of 100  cash dispenser  atomic number 19 its  book of account is reduced to 0.85  opening .\n\n allotropical modifications magnesium unknown.\n\nOn magnesium do not  conserve significant  work distilled  body of  irrigate, hydrofluoric acid, at any concentration, sediment   ary solutions of fluorides ,   reciprocal ohm (liquid and gas) , aluminum sulfate , carbon disulphide , solutions of  tart  pedestals , alkali carbonates , dry hydrocarbons ,  thorough halides containing no  intoxicant and H2O, anhydrous C2H5OH, and ethyl  acetate rayon , fats and oils not containing acids ,  evocative compounds and mineral oil.\n\n libellous  military force on magnesium  maritime and mineral water, sedimentary solutions of HCl, H2SO4, HNO3, H3PO4, fluorosilicic acid ,  sedimentary solutions of halide salts , sulfur compounds , NH3, and its aqueous solutions , NxOy, sodium hydrogen carbonate solutions ,  primitive acids , water and  soaker solvents chloro methyl group and ethyl chloride , methyl  alcoholic drink ,  dihydric alcohols and glycol mixtures , many aldehydes .\n\nAt  direction temperature in  var. magnesium compact is chemically  disgustful . On its surface an oxide  photo that protects the metal from oxidation . When  instigateed responsiveness of magnes   ium increases. It is believed that the  swiftness temperature stableness limit of magnesium to oxygen is in the range of 350 -  cd oC.\n\n milligram ignites in air at a temperature of 600-650 oC, with the organization of MgO, partially Mg3N2; at  cd - 500 oC  under(a) H2  insistence generated hydride MgH2. Reactions are  attach to by high  estrus ( to heat the glass of ice water to a boil,  equal 4 g of magnesium ) and  unseeable radiation  aright .\n\nWhen  change is reacted with magnesium to form a halogen halide , with 500 - 600 oC with sulfur form MgS; at higher(prenominal) temperature , the  administration of carbides, MgC2 and Mg2C3, silicides and MgSi Mg3Si2, phosphide Mg3P2.  
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